A one-dimensional simulation of the water vapor isotope HDO in the tropical stratosphere


Contact
Martin.Werner [ at ] awi.de

Abstract

An existing one-dimensional chemical model has been extended with dynamics and isotopic chemistry to simulate chemical production, vertical ascent, and diffusion of H216O and HDO in the tropical stratosphere. Less abundant isotopes of water vapor and methane have been added to the model's original chemical scheme. This has led to 11 additional compounds being considered, and the methane oxidation chain has been extended by 47 new reactions. The dynamical model includes vertical diffusion and a vertical ascent rate that varies throughout the year. The results of the model show values of the isotopic ratio that are expected from theoretical calculations. The δD values range from around -550‰ at the tropopause to about -300‰ at 1 hPa. The model simulations are also in agreement with the few existing measurements of δD in the stratosphere. An annual variation of the isotopic ratio at the tropopause will cause a wave pattern in the vertical profile similar to the "tape recorder effect" for water vapor. The size and shape of this annual variation is not clear, but simulations show that the effect it has on the resulting δD profile is significant. Copyright 2001 by the American Geophysical Union.



Item Type
Article
Authors
Divisions
Programs
Peer revision
Peer-reviewed
Publication Status
Published
Eprint ID
18984
DOI https://www.doi.org/10.1029/2000jd000268

Cite as
Ridal, M. , Jonsson, A. , Werner, M. and Murtagh, D. P. (2001): A one-dimensional simulation of the water vapor isotope HDO in the tropical stratosphere , Journal of Geophysical Research: Atmospheres, 106 (D23), pp. 32283-32294 . doi: https://www.doi.org/10.1029/2000jd000268


Download
[thumbnail of Fulltext]
Preview
PDF (Fulltext)
Rid2001a.pdf

Download (1MB) | Preview
Cite this document as:

Share


Citation

Research Platforms
N/A

Campaigns
N/A


Actions
Edit Item Edit Item