The surface properties of sea ice dominate many key processes and drive important feedback mechanisms in the polar oceans of both hemispheres. Examining Arctic and Antarctic sea ice, the distinctly different dominant sea-ice and snow properties in spring and summer are apparent. While Arctic sea ice features a seasonal snow cover with widespread surface ponding in summer, a year-round snow cover and strong surface flooding at the snow/ice interface is observed on Antarctic sea ice. However, substantial knowledge gaps exist about the spatial distribution and temporal evolution of these properties, and their impacts on exchange processes across the atmosphere/ocean interface. This thesis aims to overcome these limitations by quantifying the influence of surface properties on the energy and mass budgets in the ice-covered oceans. Remote sensing data and in-situ observations are combined to derive the seasonal cycle of dominant sea-ice surface characteristics, and their relation to the transfer of solar radiation from the atmosphere through snow and sea ice into the upper ocean. This thesis shows that characteristics of the solar radiation under Arctic sea ice can be described directly as a function of sea-ice surface properties as, e.g., sea-ice type and melt pond coverage. Using this parameterization, an Arctic-wide calculation of solar radiation through sea ice identifies the surface melt onset as the main driver of the annual sea-ice mass and energy budgets. In contrast, an analysis of the spring-summer transition of Antarctic sea ice using passive microwave satellite observations indicates widespread diurnal freeze-thaw cycles in the top snow layers. While the associated temporary thawing is identified as the predominant melt process, subsequent continuous melt in deeper snow layers is rarely found on Antarctic sea ice. Instead of directly influencing the snow depth on Antarctic sea ice, these melt processes rather modify the internal stratigraphy and vertical density structure of the snowpack. An additional analysis of satellite scatterometer observations reveals that snow volume loss on Antarctic sea ice is mainly driven by changes in the lower snowpack, due to the widespread presence of sea-ice surface flooding and snow-ice formation prior to changes in the upper snowpack. As a consequence, the largely heterogeneous and metamorphous Antarctic snowpack prevents a direct correlation between surface properties and the respective characteristics of the penetrating solar radiation under the sea ice. However, surface flooding is identified as the key process governing the variability of the under-ice light regime on small scales. Overall, this thesis highlights that the mass and energy budgets of Antarctic sea ice are determined by processes at the snow/ice interface as well as the temporal evolution of physical snowpack properties. These results are in great contrast to presented studies on Arctic sea ice, where seasonally alternating interactions at the atmosphere/snow- or atmosphere/sea-ice interface control both the energy and mass budgets. An improved understanding of the seasonal cycle of dominant sea-ice and snow surface characteristics in the Arctic and Antarctic is crucial for future investigations retrieving sea-ice variables, such as sea-ice thickness and snow depth, from recent microwave satellite observations.